Ralph Fiennes
Ralph Fiennes did end up part of the 007 franchise, but he nearly played Bond himself.
After Timothy Dalton left following 1989's Licence To Kill, the Harry Potter star met with then-producer Albert 'Cubby' Broccoli.
He previously recalled: "I don’t think I felt ready to commit, and I think they were looking at Pierce. I think I would have been a terrible Bond anyway.”