Natalie Wood and Robert Wagner
The actress first married Wagner when she was just 19 in 1957 but they separated four years later and divorced the following year.
The pair reunited and tied the knot for a second time in 1972 but things would come to a tragic end as the 'West Side Story' star drowned in mysterious circumstances while on a boat trip with her husband and 'Brainstorm' co-star Christopher Walken in 1981.