Jennifer Aniston and Brad Pitt

The former 'Friends' actress and 'Fight Club' star Brad were one of Hollywood's hottest couples in the early 2000s and but the pair divorced in 2005 amid rumours that he had become infatuaded with 'Mr and Mrs Smith' co-star Angelina Jolie, whom he later went on to marry and is currently enduring another messy divorce battle with her.

Jennifer - who is thought to have got 50 per cent of what Brad had earned during their time together - later said when Brad had established himself with Angelina: "I can’t say it was one of the highlights of my year. Who would deal with that and say, ‘Isn’t that sweet! That looks like fun!’? But s*** happens!"