Mr. & Mrs. Smith (2005)

It was on the set of the 2005 action comedy that Brad Pitt and Angelina Jolie met and fell in love.

They play married assassins, unaware of each other's true identities. When they discover the truth, their marriage is reignited with excitement.

The film's blend of humor, romance, and action provided the backdrop for the real-life romance that blossomed between Pitt and Jolie during the making of the movie.

Their on-screen chemistry and off-screen relationship captured the public's attention, making 'Mr. & Mrs. Smith' not only a box office success but also the beginning of a high-profile Hollywood love story.