Gwyneth Paltrow

Brad met met fellow Oscar-winner Gwyneth Paltrow when she played his wife in the thriller 'Se7en' in 1995 and the pair soon got together. The following year, Brad called Gwyneth the love of [his] life" and they got engaged but had called the whole thing off by 1997.

Gwyneth recalled: "I wish I remembered exactly what he said, but he proposed, it was fantastic, I was thrilled. We had talked about it, but I was surprised in the moment, I remember that. I must have been 24."